Oobleck has lengthy been my favourite instance of a non-Newtonian fluid, and I’m not alone. It’s a vastly fashionable “kitchen science” experiment as a result of it is easy and straightforward to make. Mix one half water to 2 elements corn starch, add a splash of meals coloring for enjoyable, and you have received oobleck, which behaves as both a liquid or a solid, relying on how a lot stress is utilized. Stir it slowly and steadily, and it is a liquid. Punch it laborious, and it turns extra solid beneath your fist. You may even fill small swimming pools with the stuff and stroll throughout it since the oobleck will harden each time you step down—a showy physics demo that naturally reveals up rather a lot on YouTube.
The underlying physics rules of this straightforward substance are surprisingly nuanced and advanced, and thus fascinating to scientists. Molecular engineers at the University of Chicago have used dense suspensions of piezoelectric nanoparticles to measure what is going on at the molecular stage when oobleck transitions from liquid to solid conduct, in line with a brand new paper revealed in the Proceedings of the National Academy of Sciences.
Toward the finish of his life, Isaac Newton laid out the properties of an “excellent liquid.” One of these properties is viscosity, loosely outlined as how a lot friction/resistance there’s to circulate in a given substance. The friction arises as a result of a flowing liquid is basically a sequence of layers sliding previous each other. The sooner one layer slides over one other, the extra resistance there’s; the slower one layer slides over one other, the much less resistance there’s. But the world is just not a perfect place.
In Newton’s excellent fluid, the viscosity largely is dependent upon temperature and strain: water will proceed to circulate regardless of different forces performing upon it, corresponding to being stirred or combined. In a non-Newtonian fluid, the viscosity modifications in response to an utilized pressure or shearing pressure, thereby straddling the boundary between liquid and solid conduct. Stirring a cup of water produces a shearing pressure, and the water shears to maneuver out of the approach. The viscosity stays unchanged. But for non-Newtonian fluids like oobleck, the viscosity modifications when a shearing pressure is utilized.
Ketchup, as an example, is a shear-thickening non-Newtonian fluid, which is one purpose smacking the backside of the bottle does not make the ketchup come out any sooner; the software of pressure will increase the viscosity. Blood, yogurt, gravy, mud, pudding, and thickened pie fillings are different examples. And so is oobleck. (The title derives from a 1949 Dr. Seuss youngsters’s ebook, Bartholomew and the Oobleck.) By distinction, non-drop paint reveals a “shear-thinning” impact, brushing on simply however changing into extra viscous as soon as it is on the wall.
In 2019, MIT researchers developed a useful mathematical mannequin to foretell how oobleck goes from liquid to solid and again once more beneath totally different circumstances. They tailored their working mannequin for moist sand, a granular materials. There are some similarities however the corn starch particles in oobleck are one-hundredth the measurement of grains of sand (between 1 to 10 microns). At these small measurement scales, the physics is markedly totally different. For occasion, temperature has extra of an influence on corn starch particles, as do electrical costs, which construct up between particles to trigger a repulsion impact. So, whereas moist sand has the similar viscosity at any given packing density regardless of the stress utilized (e.g., stirring or punching), oobleck’s viscosity modifications dramatically.
The MIT crew particularly added a “clumpiness variable” to their mannequin, describing the quantity of frictional contact between corn starch particles versus lubricated contact to foretell how that new variable would change in response to totally different stresses. Then, they ran laptop simulations of prior lab experiments—which concerned squeezing and shearing oobleck between two plates and capturing a simulated small projectile right into a tank of oobleck—to check the mannequin’s predictions. Those simulations matched the experimental outcomes from the earlier research.